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The ability of surfactants to interact with CO₂ is essential if the CO₂ is intended to augment a water flooding process as a method to displace oil from a reservoir.  In contact with oil, CO₂ lowers the oil viscosity, causes the oil to swell, overcome the high interfacial tension between oil and rock, dislodge the immobile oil and hence increase the volumetric sweep efficiency. The surfactant must possess suitable structure in order to successfully play these roles. In this context, a new surfactant with different functionalities has been synthesized to examine its CO₂ philicity. The Williamson synthesis was employed to convert the long chain alcohol and trans aconitic acid for the triple tailed structure, then sulphonated using sodium bisulfite. The response surface methodology (RSM) was employed to optimize the yield and provide the shortest reaction time using less stringent reaction conditions. A yield of 95% has been achieved using the RSM. The extent of reaction was monitored by FTIR and the final structure was validated using NMR technique. The synthesized surfactants were evaluated for EOR suitability by firstly examining the fluid – fluid compatibility (in different temperatures, salinity and harness tolerance). The ability for foaming is also assessed. The interfacial tension (IFT) between surfactant and CO₂ gas at 90^oC and upto 2700 psi showed some interesting findings. The IFT of CO₂ - brine without surfactant dropped from a value of 70 mN/m to 30 mN/m when the critical pressure approached (1070 psi). It remained 30 mN/m at higher pressures. When surfactant is incorporated the minimum IFT achieved was 1.76 mN/m after the critical pressure is reached. The foam stability of the surfactants was evaluated.  The MRF values reflect the same trend as IFT lowering and foam stability. Three tailed surfactant has the MRF of 3.4. AOS (commercial surfactant) MRF was 1.3. It appears that the surfactant having structure which demonstrates favorable CO₂ affinity has the largest IFT reduction, highest foam stability and MRF values. This trend is also repeated in the recovery factor achieved by the surfactants when core flood are performed at 90^oC and with a working pressure of 1800 psi. The three tailed surfactant provides the highest RF of 96% ROOIP. The adsorption of the surfactant was kept low at less than 0.5 mg/g.